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Reductive elimination reactions, in which a transition metal catalyzes new bond formation between two molecules, are one of organic chemists’ most powerful tools. For example, one flavor of ...
Examples of catalysis in cage cavities now range from the Knoevenagel reaction 20 to the enantioselective hydrolysis of an organophosphate dichloride 21, with the best example reported so far ...
This transformation — the conversion of an alkoxy ether to an alkoxide — represents a textbook example of a thermal E1cB-elimination reaction, which is expected to proceed with a very low ...
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